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Matter and Separation of Mixtures

Matter and Separation of Mixtures

Chemistry · 5 min read

What is matter

Matter is anything that has mass and occupies space. Everything around us (air, water, wood, stone) is matter; light, heat, sound and thoughts are not. Matter is made of particles that are extremely small, have spaces between them, are always moving, and attract each other.

  • Diffusion: particles of different substances mix on their own (smell of perfume, ink in water). It is fastest in gases, slowest in solids, and increases with temperature.
  • Brownian motion: random zig-zag motion of tiny particles in a fluid, caused by bumping of fast-moving molecules (Robert Brown).

States of matter

PropertySolidLiquidGas
ShapeFixedTakes the shape of the containerNo fixed shape
VolumeFixedFixedNot fixed
CompressibilityNegligibleVery smallHigh
Particle spacingVery closeCloseFar apart
AttractionStrongestMediumVery weak
FlowNoYesYes
ExamplesIce, wood, ironWater, milk, oilAir, oxygen, steam
  • Plasma (ionised gas, the fourth state: Sun, stars, lightning, neon signs) and Bose-Einstein condensate (very near absolute zero) are other states.
  • LPG is liquefied under pressure; CNG is compressed natural gas; dry ice is solid carbon dioxide (sublimes, no liquid stage).

Changes of state

ChangeName
Solid to liquidMelting (fusion)
Liquid to solidFreezing (solidification)
Liquid to gasVaporisation (evaporation, boiling)
Gas to liquidCondensation
Solid to gas directlySublimation (camphor, naphthalene, ammonium chloride, iodine, dry ice)
Gas to solid directlyDeposition
  • Melting point of ice = 0 C (273 K); boiling point of water = 100 C (373 K).
  • Latent heat is the heat absorbed at constant temperature during a change of state.
  • Evaporation happens at all temperatures, only at the surface, and causes cooling. It rises with higher temperature, larger surface, lower humidity and more wind. Boiling happens at one fixed temperature, throughout the liquid.
  • Pressure raises the boiling point. A pressure cooker cooks quickly; at high altitude water boils at a lower temperature.

Physical and chemical change

Physical changeChemical change
No new substance is formed; usually reversibleA new substance forms; usually irreversible
Melting ice, dissolving salt, folding paperRusting, burning, cooking, curdling of milk, souring, photosynthesis, digestion

Signs of a chemical change: change of colour, gas released, heat or light, precipitate, change of smell.

Pure substances and mixtures

TypeMeaningExamples
ElementOne kind of atom; cannot be broken furtherIron, oxygen, gold, mercury, carbon
CompoundTwo or more elements chemically combined in a fixed ratioWater, salt, sugar, CO2
MixtureTwo or more substances physically mixed; no fixed ratio; properties of components remainAir, sea water, soil, alloys
  • Homogeneous mixture: uniform throughout (a solution): salt in water, air, brass, vinegar. Heterogeneous mixture: not uniform: sand and water, oil and water.
  • Alloys are homogeneous mixtures of metals, e.g. brass (copper and zinc), bronze (copper and tin), steel (iron and carbon), solder (tin and lead), stainless steel (iron, chromium, nickel).
  • Element examples: gold, silver, copper, mercury (liquid metal), bromine (liquid non-metal); liquid at room temperature: mercury, bromine (also gallium and caesium on warm days).

Solutions, suspensions and colloids

FeatureSolutionColloidSuspension
Particle sizeSmallest (below 1 nm)1 to 1000 nmLarger than 1000 nm
AppearanceClear, transparentCloudy; scatters light (Tyndall effect)Opaque
Settles on standingNoNoYes
FiltrationCannot separateCannot separateSeparated
ExamplesSugar in water, salt waterMilk, blood, fog, smoke, jelly, ink, butter, cheeseMuddy water, chalk in water
  • Solute is dissolved; solvent dissolves it. Water is the universal solvent.
  • Tyndall effect: scattering of a light beam by colloidal particles (a sunbeam through a dusty room, headlights in fog).
  • Concentration mass percent = (mass of solute / mass of solution) x 100.
  • Saturated solution: cannot dissolve more solute at that temperature. Solubility generally increases with temperature for solids; gases dissolve less in warm water.

Methods of separation

MethodUsed forExample
HandpickingLarge impuritiesStones from rice
WinnowingLight and heavy particles using windGrain from husk
ThreshingGrain from stalksWheat
SievingDifferent sizesFlour from bran
Sedimentation and decantationInsoluble heavier solid in liquidMuddy water
FiltrationInsoluble solid from liquidTea leaves, water purification
EvaporationSoluble solid from solutionSalt from sea water
CrystallisationPure crystals from solutionSugar, alum, copper sulphate
Magnetic separationMagnetic from non-magneticIron filings from sand
SublimationA sublimable solid from a mixtureAmmonium chloride from salt
CentrifugationTiny suspended particlesCream from milk, blood cells
Separating funnelTwo immiscible liquidsOil and water
Simple distillationLiquid from a dissolved solidPure water from salt water
Fractional distillationLiquids with close boiling pointsAir gases, petroleum, alcohol and water
ChromatographyDyes and pigmentsInk colours, plant pigments
Loading (adding alum)Fine suspended clayWater purification

Purification of drinking water: sedimentation, filtration, chlorination (kills germs), boiling and UV or RO.

Keep practising

Notes are only half the work. Test yourself with questions and discuss doubts with other aspirants.

Prepared for exam revision from the NCERT Science textbooks for Classes 6 to 10 and standard sources. Space missions, awards and records change, so check official sources for recent facts. Found a mistake? Tell us.